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1-{[(Cyclo-hexyl-oxy)carbon-yl]-oxy}ethyl 3-{[2'-(2-ethyl-2H-tetra-zol-5-yl)biphenyl-4-yl]meth-yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl-ate.

ABSTRACT: In the title compound, C(33)H(34)N(6)O(6), the dihydro-benzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021?Å). The cyclo-hexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetra-zole fragment, the tetra-zole ring is twisted away from the attached benzene ring by 35.73?(11)° and the two benzene rings form a dihedral angle of 68.00?(9)°. An intra-molecular C-H?O inter-action is observed. In the crystal, the mol-ecules are linked into a zigzag chain running along the b axis by inter-molecular N-H?O hydrogen bonds.

SUBMITTER: Mohan A

PROVIDER: S-EPMC2983784 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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1-{[(Cyclo-hexyl-oxy)carbon-yl]-oxy}ethyl 3-{[2'-(2-ethyl-2H-tetra-zol-5-yl)biphenyl-4-yl]meth-yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl-ate.

Mohan A A Ramesh P P Saravanan D D Ponnuswamy M N MN

Acta crystallographica. Section E, Structure reports online 20100331 Pt 4

In the title compound, C(33)H(34)N(6)O(6), the dihydro-benzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021 Å). The cyclo-hexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetra-zole fragment, the tetra-zole ring is twisted away from the attached benzene ring by 35.73 (11)° and the two benzene rings form a dihedral angle of 68.00 (9)°. An intra-molecular C-H⋯O inter-action is observed. In the crystal, the mol-ecules are linked into a zigzag chain runn ...[more]

PMID: 21580794

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