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Flexible two-dimensional square-grid coordination polymers: structures and functions.

ABSTRACT: Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4'-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-organic frameworks (ELMs). Such a unique property can make it possible to overcome the dilemma of strong adsorption and easy desorption, which is one of the ideal properties for practical adsorbents.

SUBMITTER: Kajiro H

PROVIDER: S-EPMC2996794 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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Flexible two-dimensional square-grid coordination polymers: structures and functions.

Kajiro Hiroshi H Kondo Atsushi A Kaneko Katsumi K Kanoh Hirofumi H

International journal of molecular sciences 20100930 10

Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4'-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-or ...[more]

PMID: 21152303

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