Ontology highlight
ABSTRACT:
SUBMITTER: Ranade SC
PROVIDER: S-EPMC3005820 | biostudies-literature | 2010 Dec
REPOSITORIES: biostudies-literature
Organic letters 20101118 24
It is reported that S-glycosyl O-methyl phenylcarbamothioates (SNea carbamothioates) have a fully orthogonal character in comparison to S-benzoxazolyl (SBox) glycosides. This complete orthogonality was revealed by performing competitive glycosylation experiments in the presence of various promoters. The results obtained indicate that SNea carbamothioates have a very similar reactivity profile to that of glycosyl thiocyanates, yet are significantly more stable and tolerate selected protecting gro ...[more]