Ontology highlight
ABSTRACT:
SUBMITTER: Wang T
PROVIDER: S-EPMC6656396 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
European journal of organic chemistry 20180913 47
Glycosyl nitrates are important synthetic intermediates in the synthesis of 2-amino sugars, 1,2-orthoesters or, more recently, 2-OH glucose. However, glycosyl nitrates have never been glycosidated. Presented herein is our first attempt to use glycosyl nitrates as glycosyl donors for <i>O</i>-glycosylation. Lanthanide triflates showed good affinity to activate the nitrate leaving group. ...[more]