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(2-Meth-oxy-benz-yl)(2-meth-oxy-benzyl-idene)aza-nium (2-meth-oxy-phen-yl)methanaminium tetra-chloridozincate(II) monohydrate.

ABSTRACT: The title compound, (C(8)H(12)NO)(C(16)H(18)NO(2))[ZnCl(4)]·H(2)O, was obtained as a by-product of the Zn(2+) and HCl catalyzed condensation of (2-meth-oxy-phen-yl)methanamine in water. Both cations feature an intra-molecular N-H?O hydrogen bond. In the crystal, the components are linked by an extensive three-dimensional network of N-H?O, O-H?Cl and N-H?Cl hydrogen bonds (three of them bifurcated). Weak C-H?O intera-ctions also occur.

SUBMITTER: El Glaoui M

PROVIDER: S-EPMC3006710 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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(2-Meth-oxy-benz-yl)(2-meth-oxy-benzyl-idene)aza-nium (2-meth-oxy-phen-yl)methanaminium tetra-chloridozincate(II) monohydrate.

El Glaoui Meher M Jeanneau Erwann E Zeller Matthias M Lefebvre Frederic F Ben Nasr Cherif C

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

The title compound, (C(8)H(12)NO)(C(16)H(18)NO(2))[ZnCl(4)]·H(2)O, was obtained as a by-product of the Zn(2+) and HCl catalyzed condensation of (2-meth-oxy-phen-yl)methanamine in water. Both cations feature an intra-molecular N-H⋯O hydrogen bond. In the crystal, the components are linked by an extensive three-dimensional network of N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds (three of them bifurcated). Weak C-H⋯O intera-ctions also occur. ...[more]

PMID: 21587715

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