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Catena-Poly[[aqua-(imidazole)-cadmium(II)]-?(3)-benzene-1,3-dicarboxyl-ato].

ABSTRACT: In the title compound, [Cd(C(8)H(4)O(4))(C(3)H(4)N(2))(H(2)O)](n), the Cd(II) ion is seven-coordinated by five O atoms from three crystallographically independent benzene-1,3-carboxylate ligands, one N atom from the imidazole ligand and one coordinated water mol-ecule. Neighboring Cd(II) ions are bridged by the benzene-1,3-dicarboxyl-ate ligands, forming a zigzag polymeric chain structure. These chains are further extended into a three-dimensional supra-molecular structure through O-H?O and N-H?O hydrogen bonds.

SUBMITTER: Zeng Z

PROVIDER: S-EPMC3006711 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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catena-Poly[[aqua-(imidazole)-cadmium(II)]-μ(3)-benzene-1,3-dicarboxyl-ato].

Zeng Zhengfang Z Xu Hongyan H

Acta crystallographica. Section E, Structure reports online 20100616 Pt 7

In the title compound, [Cd(C(8)H(4)O(4))(C(3)H(4)N(2))(H(2)O)](n), the Cd(II) ion is seven-coordinated by five O atoms from three crystallographically independent benzene-1,3-carboxylate ligands, one N atom from the imidazole ligand and one coordinated water mol-ecule. Neighboring Cd(II) ions are bridged by the benzene-1,3-dicarboxyl-ate ligands, forming a zigzag polymeric chain structure. These chains are further extended into a three-dimensional supra-molecular structure through O-H⋯O and N-H⋯ ...[more]

PMID: 21587718

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