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Bis(ferrocene-carboxyl-ato-?O)bis-(2-pyridyl-methanol-?N,O)cobalt(II).

ABSTRACT: The title complex mol-ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa-hedral coordination geometry, provided by the O atoms of two monodentate ferrocene-carboxyl-ate anions and by the N and O atoms of two 2-pyridyl-methanol mol-ecule. The mol-ecular conformation is stabilized by intra-molecular C-H?O hydrogen bonds.

SUBMITTER: Yu Y

PROVIDER: S-EPMC3007041 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Bis(ferrocene-carboxyl-ato-κO)bis-(2-pyridyl-methanol-κN,O)cobalt(II).

Yu Youzhu Y Guo Yuhua Y Wang Daqi D Li Dacheng D

Acta crystallographica. Section E, Structure reports online 20100605 Pt 7

The title complex mol-ecule, [Fe(2)Co(C(5)H(5))(2)(C(6)H(4)O(2))(2)(C(6)H(7)NO)(2)], has a crystallographic imposed centre of symmetry. The Co(II) atom displays a distorted octa-hedral coordination geometry, provided by the O atoms of two monodentate ferrocene-carboxyl-ate anions and by the N and O atoms of two 2-pyridyl-methanol mol-ecule. The mol-ecular conformation is stabilized by intra-molecular C-H⋯O hydrogen bonds. ...[more]

PMID: 21587689

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