Ontology highlight
ABSTRACT:
SUBMITTER: Fu XQ
PROVIDER: S-EPMC3007073 | biostudies-literature | 2010 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100605 Pt 7
The title compound, (C(7)H(8)NO)(6)[Sb(4)Cl(18)], contains centrosymmetric hexa-anions built up from four vertex-sharing alternating SbCl(5) square-based pyramids and highly distorted SbCl(6) octa-hedra when long (<3.2 Å) 'secondary' Sb-Cl inter-actions are taken into account. The inter-polyhedral Sb-Cl bonds define a square-shape. In the crystal, the components are linked by N-H⋯Cl, C-H⋯Cl and C-H⋯O hydrogen bonds, generating a three-dimensional network. ...[more]