Browse
Submit Data
Databases
API
Help

Dataset Information

16 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[bis-[octa-kis(dimethyl sulf-oxide)praseodymium(III)] hexa-?(3)-sulfido-dodeca-?(2)-sulfido-hexa-sul-fido-hexa-silverhexa-molybdenum].

ABSTRACT: The title compound, {[Pr(C(2)H(6)OS)(8)](2)[Mo(6)Ag(6)S(24)]}(n), contains polymeric Mo(6)S(24)Ag(6) (2-) anions and [Pr(Me(2)SO)(8)](3+) cations, forming a one-dimensional polymeric Mo/S/Ag cluster. The anion assumes the conformation of a zigzag chain. The trivalent cations are arrayed amongst the anionic chains and are well separated from each other. Each Mo and Ag atom is coordinated by four S atoms in a distorted tetra-hedral geometry. The Pr(3+) atom is coordinated by eight dimethyl sulfoxide ligands, forming a polyhedron-shaped distorted square anti-prism.

SUBMITTER: Jiang Z

PROVIDER: S-EPMC2962003 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[bis-[octa-kis(dimethyl sulf-oxide)praseodymium(III)] hexa-μ(3)-sulfido-dodeca-μ(2)-sulfido-hexa-sul-fido-hexa-silverhexa-molybdenum].

Jiang Zhengjing Z Tang Guodong G Li Rongqing R Zhang Yu Y

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

The title compound, {[Pr(C(2)H(6)OS)(8)](2)[Mo(6)Ag(6)S(24)]}(n), contains polymeric Mo(6)S(24)Ag(6) (2-) anions and [Pr(Me(2)SO)(8)](3+) cations, forming a one-dimensional polymeric Mo/S/Ag cluster. The anion assumes the conformation of a zigzag chain. The trivalent cations are arrayed amongst the anionic chains and are well separated from each other. Each Mo and Ag atom is coordinated by four S atoms in a distorted tetra-hedral geometry. The Pr(3+) atom is coordinated by eight dimethyl sulfoxi ...[more]

PMID: 21203073

Similar Datasets

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?O,O')dysprosium(III)] [molybdenum(VI)-di-?-sulfido-silver(I)-di-?-sulfido]].

Project description:Hexamethyl-phospho-ramide (hmp), tetra-thio-molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n-) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-anti-prismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo-Ag-Mo and Ag-Mo-Ag angles of 161.911?(13) and 154.014?(13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue.

| S-EPMC3009021 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?O,O')yttrium(III)] [silver(I)-di-?-sulfido-molybdenum(VI)-di-?-sulfido]].

Project description:In the cation of the title compound, {[Y(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n), the Y atom is coordinated by eight O atoms from two chelating nitrate groups and four hexa-methyl-phospho-ramide (hmp) ligands, which gives rise to a distorted square-anti-prismatic environment. Together with the two nitrate ligands, the overall charge for the complex cation is +1, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain, with Mo-Ag-Mo and Ag-Mo-Ag angles of 161.916?(13) and 153.915?(13)°, respectively, presents a distorted linear configuration. The cations and the anions are linked via weak C-H?S hydrogen-bonding inter-actions while the cations exhibit inter-molecular C-H?O inter-actions. The structure is isotypic with the corresponding W, Yb, Eu, Nd, La and Dy complexes.

| S-EPMC3200717 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?O,O')samarium(III)] [silver(I)-di-?-sulfido-tungstate(VI)-di-?-sulfido]].

Project description:The Sm atom in the cation of the title salt, {[Sm(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgS(4)W]}(n), is coordinated by eight O atoms derived from two chelating nitrate anions, and four hexamethylphos-phoramide ligand, defining a distorted square-antiprismatic geometry. The anions self-assemble into polymeric chains via W-S-Ag bridges having a [AgS(4)W] repeat unit; the W-Ag-W and Ag-W-Ag angles are 161.657?(17) and 153.978?(9)°, respectively. The title complex is isostructural with the Y, Yb, Eu, Nd, La and Dy isomorphs.

| S-EPMC3201561 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?O,O')cerium(III)] [silver(I)-di-?-sulfido-tungstate(VI)-di-?-sulfido]].

Project description:Hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver sulfide and cerium nitrate were self-assembled to form a one-dimensional anionic [Ag(4)W(4)S(16)](n) (4n-) chain in the title compound, {[Ce(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The asymmetric unit contains four crystallographically independent [Ce(hmp)(4)(NO(3))(2)](+) cations, which leads to a one-dimensional polymeric anionic chain having a tetra-valent [W(4)S(16)Ag(4)] repeat unit. Each central Ce atom is coordinated by eight O atoms from two chelating nitrate and four hmp ligands, which gives rise to a distorted square-anti-prismatic structure. The polymeric chain with average W-Ag-W and Ag-W-Ag bond angles of 163.75 and 151.84°, respectively, presents a distorted linear configuration. The title complex with a non-centrosymmetric structure, is analogous to the Yb, Y, Eu, Nd, La and Dy isomorphs, which exhibit centrosymmetric structures.

| S-EPMC3011570 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?O,O')holmium(III)] [silver(I)-di-?-sulfido-tungstate(VI)-di-?-sulfido]].

Project description:In the title salt, {[Ho(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the anion forms a W/S/Ag polymeric chain along the a axis. The holmium atom in the cation is coordinated by eight O atoms from two nitrate and four hexa-methyl-phospho-ramide ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the complex cation in the title compound is univalent, which leads the anion to be univalent as well. The polymeric anionic chain with W-Ag-W and Ag-W-Ag angles of 161.429?(17) and 153.608?(10) °, respectively, presents a distorted linear configuration. The title complex is isotypic with the corresponding Y, Yb, Eu, Nd, La and Dy analogues.

| S-EPMC3238639 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?(2)O,O')lutetium(III)] [silver(I)-di-?-sulfido-tungstate(VI)-di-?-sulfido]].

Project description:In the title compound, {[Lu(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver iodide and lutetium nitrate were self-assembled, forming an anionic {[AgWS(4)](-)}(n) chain extending parallel to [001]. The Lu(III) atom in the cation is coordinated by eight O atoms from two nitrate groups and four hmp ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate groups, the cation is monovalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration with W-Ag-W and Ag-W-Ag angles of 161.66?(2) and 153.503?(12)°, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy and Sm analogues.

| S-EPMC3379104 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?(2)O,O')terbium(III)] [silver(I)-di-?-sulfido-tungstate(VI)-di-?-sulfido]].

Project description:In the title compound, {[Tb(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the polymeric anionic chain {[AgWS(4)](-)}(n) extends along [001]. The Tb(III) atom in the cation is coordinated by eight O atoms from two nitrate and four hexamethylphosphate ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the cation is univalent, which leads to the anionic chain having a [WS(4)Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration with W-Ag-W and Ag-W-Ag angles of 161.49?(2) and 153.743?(13) °, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy, Sm and Lu analogues.

| S-EPMC3379183 | biostudies-literature

catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?(2) O,O')erbium(III)] [silver(I)-di-?-sulfido-tungstate(VI)-di-?-sulfido]].

Project description:In the title compound, {[Er(NO3)2(C6H18N3OP)4][AgWS4]} n , the polymeric anionic chain {[AgWS4](-)} n extends along [001]. The Er(III) atom in the cation is coordinated by eight O atoms from two bidentate nitrate anions and four hexa-methyl-phospho-ramide ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a [WS4Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration, with W-Ag-W and Ag-W-Ag angles of 161.37?(2) and 153.548?(12)°, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy, Sm, Lu and Tb analogues.

| S-EPMC3588238 | biostudies-literature

Octa-kis(dimethyl sulfoxide-?O)cerium(III) ?(6)-oxido-dodeca-?(2)-oxido-hexa-oxidohexa-molybdate(VI) dimethyl sulfoxide tetrasolvate.

Project description:The title complex, [Ce(C(2)H(6)OS)(8)](2)[Mo(6)O(19)](3)·4C(2)H(6)OS, was obtained as a byproduct of the reaction of [(C(4)H(9))(4)N](2)[Mo(6)O(19)] with Ce(NO(3))(3)·6H(2)O and phthalic acid in dimethyl-sulfoxide solution. The asymmetric unit consists of a complex [Ce(C(2)H(6)OS)(8)](3+) cation, one and a half of the Lindqvist-type [Mo(6)O(19)](2-) polyanions and two dimethyl-sulfoxide solvent mol-ecules; the half polyanion lies on an inversion center. The Ce(3+) ion is coordinated by eight dimethyl-sulfoxide ligands through the O atoms in the form of a distorted square antiprism. The Ce-O bond lengths range from 2.429?(6) to 2.550?(5)?Å. The cohesion of the structure is ensured by S?O [3.115?(6), 3.242?(10) and 3.12?(3)?Å], O?O [3.037?(10)?Å] and C-H?O inter-actions between cations and anions. The S and C atoms of a dmso ligand are disordered over three sites in a 0.45:0.30:0.25 ratio. The dimethyl-sulfoxide solvent mol-ecules are highly disordered and could not be modelled successfully; their contribution was therefore removed from the refinement using the SQUEEZE routine in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155]. Potential solvent-accessible voids of 500.0?Å(3) occur in the crystal structure.

| S-EPMC3393199 | biostudies-literature

catena-Poly[[tetra-kis(hexa-methyl-phospho-ramide-?O)bis-(nitrato-?O,O')lanthanum(III)] [silver(I)-di-?(2)-sulfido-tungstate(VI)-di-?(2)-sulfido]].

Project description:Hexamethyl-phospho-ramide (hmp), tetra-thio-tungstate(VI), silver sulfide and lanthanum(III) nitrate are self-assembled to form discrete cations one-dimensional poylmeric anionic chains [AgWS(4)](n) (n) (-) in the title compound, {[La(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central La atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a monovalent repeat unit. The polymeric anionic chain with W?Ag?W and Ag?W?Ag angles of 165.94?(3) and 155.894?(14)° presents a distorted linear configuration. Five N atoms, 18 C atoms and their attached H atoms are disordered equally over two positions.

| S-EPMC2960413 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data