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(E)-1-(2,4-Dinitro-phen-yl)-2-[1-(thio-phen-2-yl)ethyl-idene]hydrazine.

ABSTRACT: The mol-ecule of the title compound, C(12)H(10)N(4)O(4)S, is slightly twisted, with a dihedral angle of 8.23?(9)° between the benzene and thio-phene rings. One nitro group is co-planar [O-N-C-C torsion angles = -0.5?(3) and -1.9?(3)°] whereas the other is slightly twisted with respect to the benzene ring [O-N-C-C torsion angles = -5.1?(3) and -5.7?(3)°]. In the crystal, the mol-ecules are linked by weak C-H?O inter-actions into screw chains along the b axis. The mol-ecular conformation is consolidated by an intra-molecular N-H?O hydrogen bond.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3089201 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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(E)-1-(2,4-Dinitro-phen-yl)-2-[1-(thio-phen-2-yl)ethyl-idene]hydrazine.

Fun Hoong-Kun HK Jansrisewangwong Patcharaporn P Chantrapromma Suchada S

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

The mol-ecule of the title compound, C(12)H(10)N(4)O(4)S, is slightly twisted, with a dihedral angle of 8.23 (9)° between the benzene and thio-phene rings. One nitro group is co-planar [O-N-C-C torsion angles = -0.5 (3) and -1.9 (3)°] whereas the other is slightly twisted with respect to the benzene ring [O-N-C-C torsion angles = -5.1 (3) and -5.7 (3)°]. In the crystal, the mol-ecules are linked by weak C-H⋯O inter-actions into screw chains along the b axis. The mol-ecular conformation is consol ...[more]

PMID: 21754363

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