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(E,E)-1,2-Bis[1-(2-bromo-phen-yl)ethyl-idene]hydrazine.


ABSTRACT: In the title compound, C(16)H(14)Br(2)N(2), the complete molecule is generated by a crystallographic twofold axis. The dihedral angle between the two benzene rings is 35.28?(8)° and that between the best planes of two ethyl-idinehydrazine N-N=C-Me units is 87.67?(11)°. Each of these N/N/C/C planes makes a dihedral angle of 63.81?(10)° with the adjacent benzene ring. In the crystal, the mol-ecules are arranged into a layer parallel to the ac plane through C-H?? inter-actions. C?Br short contacts [3.4032?(18)-3.5969?(19)?Å] are also observed.

SUBMITTER: Jansrisewangwong P 

PROVIDER: S-EPMC3007455 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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(E,E)-1,2-Bis[1-(2-bromo-phen-yl)ethyl-idene]hydrazine.

Jansrisewangwong Patcharaporn P   Chantrapromma Suchada S   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8


In the title compound, C(16)H(14)Br(2)N(2), the complete molecule is generated by a crystallographic twofold axis. The dihedral angle between the two benzene rings is 35.28 (8)° and that between the best planes of two ethyl-idinehydrazine N-N=C-Me units is 87.67 (11)°. Each of these N/N/C/C planes makes a dihedral angle of 63.81 (10)° with the adjacent benzene ring. In the crystal, the mol-ecules are arranged into a layer parallel to the ac plane through C-H⋯π inter-actions. C⋯Br short contacts  ...[more]

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