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Dicyanidobis(thio-urea-?S)cadmium(II) monohydrate.

ABSTRACT: In the title compound, [Cd(CN)(2)(CH(4)N(2)S)(2)]·H(2)O, the Cd atom lies on a twofold rotation axis and is bonded to two S atoms of thio-urea and two C atoms of the cyanide anions in a distorted tetra-hedral environment. The crystal structure is stabilized by N-H?N(CN), N-H?O, O-H?N and N-H?S hydrogen bonds.

SUBMITTER: Fettouhi M

PROVIDER: S-EPMC3007584 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Dicyanidobis(thio-urea-κS)cadmium(II) monohydrate.

Fettouhi Mohammed M Riaz Malik Muhammad M Ali Saqib S A Isab Anvarhusein A Ahmad Saeed S

Acta crystallographica. Section E, Structure reports online 20100724 Pt 8

In the title compound, [Cd(CN)(2)(CH(4)N(2)S)(2)]·H(2)O, the Cd atom lies on a twofold rotation axis and is bonded to two S atoms of thio-urea and two C atoms of the cyanide anions in a distorted tetra-hedral environment. The crystal structure is stabilized by N-H⋯N(CN), N-H⋯O, O-H⋯N and N-H⋯S hydrogen bonds. ...[more]

PMID: 21588216

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