Unknown

Dataset Information

0

Bromidobis(N,N'-diphenyl-thio-urea-?S)copper(I) monohydrate.

ABSTRACT: In the title compound, [CuBr(C(13)H(12)N(2)S)(2)]·H(2)O, the Cu(I) atom adopts a slightly distorted trigonal-planar coordination arising from two S atoms of two diphenyl-thio-urea ligands and a bromide ion. There are two intra-molecular N-H?Br hydrogen bonds completing twisted six-membered rings with R(6) motifs. The dihedral angles between the aromatic rings in the ligands are 62.11?(13) and 85.73?(13)°. In the crystal, components are linked by N-H?O, O-H?S and O-H?? inter-actions. There also exist ?-? inter-actions with a distance of 3.876?(2)?Å between the centroids of benzene rings of two different ligands. Together, the inter-molecular inter-actions lead to a three-dimensional network.

SUBMITTER: Mufakkar M 

PROVIDER: S-EPMC2977283 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Bromidobis(N,N'-diphenyl-thio-urea-κS)copper(I) monohydrate.

Mufakkar Muhammad M   Tahir M Nawaz MN   Ahmad Saeed S   Shaheen Muhammad Ashraf MA   Waheed Abdul A  

Acta crystallographica. Section E, Structure reports online 20090711 Pt 8

In the title compound, [CuBr(C(13)H(12)N(2)S)(2)]·H(2)O, the Cu(I) atom adopts a slightly distorted trigonal-planar coordination arising from two S atoms of two diphenyl-thio-urea ligands and a bromide ion. There are two intra-molecular N-H⋯Br hydrogen bonds completing twisted six-membered rings with R(6) motifs. The dihedral angles between the aromatic rings in the ligands are 62.11 (13) and 85.73 (13)°. In the crystal, components are linked by N-H⋯O, O-H⋯S and O-H⋯π inter-actions. There also e  ...[more]

Similar Datasets

Unknown Bis-(N,N'-diphenyl-thio-urea)iodido-copper(I) monohydrate.
| S-EPMC2961451 | biostudies-literature
Unknown N,N'-Diphenyl-thio-urea acetone monosolvate.
| S-EPMC3050175 | biostudies-literature
Unknown Dicyanidobis(thio-urea-κS)cadmium(II) monohydrate.
| S-EPMC3007584 | biostudies-literature
Unknown Di-chlorido-diphenyl-bis-(thio-urea-?S)tin(IV).
| S-EPMC3790350 | biostudies-literature
Unknown catena-Poly[[[bis-(thio-urea-κS)copper(I)]-μ-thio-urea-κS:S] iodide acetonitrile hemisolvate].
| S-EPMC2960929 | biostudies-literature
Unknown Redetermination of catena-poly[[chlorido-(thio-urea-?S)copper(I)]-?-thio-urea-?S:S] at 100?K.
| S-EPMC3297225 | biostudies-literature
Unknown Iodido(N-phenyl-thio-urea)bis-(triphenyl-phosphine)copper(I).
| S-EPMC2961665 | biostudies-literature
Unknown N-Benzoyl-N'-(1,10-phenanthrolin-5-yl)thio-urea dichloro-methane hemisolvate monohydrate.
| S-EPMC3120558 | biostudies-literature
Unknown 1-(4,6-Dimethyl-pyrimidin-2-yl)-3-(3,5-dinitro-benzo-yl)thio-urea monohydrate.
| S-EPMC3089191 | biostudies-literature
Unknown 1-(2,3,4,6-Tetra-O-acetyl-?-d-gluco-pyranos-yl)-3-thio-ureidothio-urea monohydrate.
| S-EPMC2968307 | biostudies-literature