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K(3)Gd(PO(4))(2).

ABSTRACT: The title compound, tripotassium gadolinium(III) bis-[ortho-phosphate(V)], was synthesized by a high-temperature solution reaction. Of the 12 atoms of the asymmetric unit (1 × Gd, 2 × P, 3 × K, 6 × O), all but two O atoms (which are in general positions) lie on mirror planes. The crystal structure features sheets of composition [Gd(PO(4))(2)](3-) which extend parallel to (100) and are built up from isolated PO(4) tetra-hedra and GdO(7) monocapped prisms through corner- and edge-sharing. The K(+) ions, which have coordination numbers of 10, 9 and 11, help to stack the anionic sheets along [100] into a three-dimensional structure.

SUBMITTER: Zhao D

PROVIDER: S-EPMC3008008 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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K(3)Gd(PO(4))(2).

Zhao Dan D Li Fei Fei FF

Acta crystallographica. Section E, Structure reports online 20100811 Pt 9

The title compound, tripotassium gadolinium(III) bis-[ortho-phosphate(V)], was synthesized by a high-temperature solution reaction. Of the 12 atoms of the asymmetric unit (1 × Gd, 2 × P, 3 × K, 6 × O), all but two O atoms (which are in general positions) lie on mirror planes. The crystal structure features sheets of composition [Gd(PO(4))(2)](3-) which extend parallel to (100) and are built up from isolated PO(4) tetra-hedra and GdO(7) monocapped prisms through corner- and edge-sharing. The K(+) ...[more]

PMID: 21588471

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