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Acetato-chlorido[2,2'-(ethane-1,2-di-yl)di-1H-benzimidazole]-copper(II) monohydrate.

ABSTRACT: In the title complex, [Cu(CH(3)COO)Cl(C(16)H(14)N(4))]·H(2)O, the Cu(II) ion is five-coordinated by two N atoms from a 2,2'-(ethane-1,2-di-yl)di-1H-benzimidazole ligand, two O atoms from a chelating acetate ligand and one terminal monodentate Cl atom in a distorted square-pyramidal geometry. In the crystal, adjacent mol-ecules are linked through O-H?Cl, N-H?Cl, N-H?O and O-H?O hydrogen bonds into a three-dimensional network.

SUBMITTER: Li YX

PROVIDER: S-EPMC3008101 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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Acetato-chlorido[2,2'-(ethane-1,2-di-yl)di-1H-benzimidazole]-copper(II) monohydrate.

Li Yu-Xian YX Yang Huai-Xia HX Ding Ya-Nan YN Meng Xiang-Ru XR

Acta crystallographica. Section E, Structure reports online 20100821 Pt 9

In the title complex, [Cu(CH(3)COO)Cl(C(16)H(14)N(4))]·H(2)O, the Cu(II) ion is five-coordinated by two N atoms from a 2,2'-(ethane-1,2-di-yl)di-1H-benzimidazole ligand, two O atoms from a chelating acetate ligand and one terminal monodentate Cl atom in a distorted square-pyramidal geometry. In the crystal, adjacent mol-ecules are linked through O-H⋯Cl, N-H⋯Cl, N-H⋯O and O-H⋯O hydrogen bonds into a three-dimensional network. ...[more]

PMID: 21588549

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