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Tetra-kis[?-2-(4-hy-droxy-phenyl)-acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bi-pyridine-?N)bis-[2-(4-hy-droxy-phenyl)-acetato-?O,O]neodymium(III)} monohydrate.

ABSTRACT: The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hy-droxy-phenyl-acetate (hpaa) anions, two 4,4'-bipyridine mol-ecules (bipy) and two water mol-ecules; an additional water mol-ecule of solvation is also present in the crystal structure. Each of the Nd(III) ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water mol-ecule in a distorted tricapped trigonal-prismatic geometry. The hpaa ligands are coordinated to the Nd(III) ions in the bridging and bridging tridentate modes. Extensive O-H?O, O-H?N and C-H?O hydrogen bonding stabilizes the crystal structure.

SUBMITTER: Liu JL

PROVIDER: S-EPMC3009128 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Tetra-kis[μ-2-(4-hy-droxy-phenyl)-acetato]-κO,O':O;κO:O,O'-bis-{aqua-(4,4'-bi-pyridine-κN)bis-[2-(4-hy-droxy-phenyl)-acetato-κO,O]neodymium(III)} monohydrate.

Liu Jia-Lu JL Liu Jian-Feng JF Zhao Guo-Liang GL

Acta crystallographica. Section E, Structure reports online 20101030 Pt 11

The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hy-droxy-phenyl-acetate (hpaa) anions, two 4,4'-bipyridine mol-ecules (bipy) and two water mol-ecules; an additional water mol-ecule of solvation is also present in the crystal structure. Each of the Nd(III) ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from a bipy ligand and an O atom from a water mol-ecule in a distorted tricapped trigonal-prismatic geometry ...[more]

PMID: 21588892

Similar Datasets

Bis[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bipyridine-?N)bis-[2-(4-hy-droxy-phen-yl)acetato-?O,O']ytterbium(III)} monohydrate.

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Bis[?-2-(4-hy-droxy-phen-yl)acetato]-?O,O':O;?O:O,O'-bis-{aqua-(4,4'-bi-pyridine-?N)[2-(4-hy-droxy-phen-yl)acetato-?O,O']erbium(III)} monohydrate.

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catena-Poly[[(tetra-aqua-cadmium)-?-4,4'-bipyridine-?(2)N:N'] 4-hy-droxy-3-sulfonato-benzoate monohydrate].

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| S-EPMC3379062 | biostudies-literature

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