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{6,6'-Dieth-oxy-2,2'-[4,5-dimethyl-o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}copper(II).

ABSTRACT: In the title complex, [Cu(C(26)H(26)N(2)O(4))], the Cu(II) ion lies on a crystallographic twofold rotation axis and is coordinated in a slightly distorted square-planar environment. The dihedral angle between the central benzene ring and each of the two symmetry-related outer benzene rings is 5.1?(2)°. The crystal structure is stabilized by inter-molecular ?-? inter-actions with centroid-centroid distances in the range 3.466?(2)-3.6431?(16)?Å.

SUBMITTER: Jamshidvand A

PROVIDER: S-EPMC3009165 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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{6,6'-Dieth-oxy-2,2'-[4,5-dimethyl-o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}copper(II).

Jamshidvand Arezoo A Kargar Hadi H Kia Reza R Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20101030 Pt 11

In the title complex, [Cu(C(26)H(26)N(2)O(4))], the Cu(II) ion lies on a crystallographic twofold rotation axis and is coordinated in a slightly distorted square-planar environment. The dihedral angle between the central benzene ring and each of the two symmetry-related outer benzene rings is 5.1 (2)°. The crystal structure is stabilized by inter-molecular π-π inter-actions with centroid-centroid distances in the range 3.466 (2)-3.6431 (16) Å. ...[more]

PMID: 21588889

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