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Aqua-chlorido{?-6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl-formamide solvate.

ABSTRACT: In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord-inated in a square-planar geometry by two N atoms and two O atoms of the 6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl--idyne)]diphenolate ligand. The Na(I) ion is hexa-coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water mol-ecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two phenolate O atoms.

SUBMITTER: Ma XJ 

PROVIDER: S-EPMC2980255 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Aqua-chlorido{μ-6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl-formamide solvate.

Ma Xiao-Jian XJ  

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1

In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord-inated in a square-planar geometry by two N atoms and two O atoms of the 6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl--idyne)]diphenolate ligand. The Na(I) ion is hexa-coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water mol-ecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two ph  ...[more]

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