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Aqua-(hippurato)bis-(1,10-phenanthroline)cobalt(II) nitrate monohydrate.

ABSTRACT: In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intra-molecular hydrogen bond to the coordinated water mol-ecule. The crystal packing is stabilized by inter-molecular O-H?O hydrogen bonds involving the Hc anions, the coordinated water mol-ecule, the nitrate anion and the uncoordinated water mol-ecule.

SUBMITTER: Guo GQ 

PROVIDER: S-EPMC3009208 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Aqua-(hippurato)bis-(1,10-phenanthroline)cobalt(II) nitrate monohydrate.

Guo Gui-Quan GQ   Deng Ji-Hua JH   Chen Jing J  

Acta crystallographica. Section E, Structure reports online 20101020 Pt 11

In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intra-molecular hydrogen bond to the coordinated water mol-ecule. The crystal packing is stabilized by inter-molecular O-H⋯O hydrogen bonds involving the Hc  ...[more]

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