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Aqua-(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate.

ABSTRACT: In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a ?-? stacking inter-action between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid-centroid distance = 3.567?(2)?Å and a perpendicular distance of 3.394?Å]. The crystal structure also contains inter-molecular N-H?O, O-H?O and C-H?O hydrogen bonds, linking cations and anions. In addition, there is a short inter-molecular contact [2.784?(6)?Å] between an O atom of the coordinated nitrate group and its symmetry-related atom.

SUBMITTER: Li HL

PROVIDER: S-EPMC2961415 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Aqua-(2-hydrazino-1,10-phenanthroline)nitratocopper(II) nitrate.

Li Hong Liang HL Liu Qi Sheng QS

Acta crystallographica. Section E, Structure reports online 20080530 Pt 6

In the title mononuclear complex, [Cu(NO(3))(C(12)H(10)N(4))(H(2)O)]NO(3), the Cu(II) ion assumes a distorted square-pyramidal geometry. There is a π-π stacking inter-action between the five-membered ring containing the Cu atom and a pyridine ring of a neighboring complex [centroid-centroid distance = 3.567 (2) Å and a perpendicular distance of 3.394 Å]. The crystal structure also contains inter-molecular N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds, linking cations and anions. In addition, there is a ...[more]

PMID: 21202525

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