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Bis(tetra-phenyl-arsonium) di-?-hy-droxido-bis-[(nitrilo-triacetato)-cobalt(III)] octa-hydrate.

ABSTRACT: In the title compound, (C(24)H(20)As)(2)[Co(2)(C(6)H(6)NO(6))(2)(OH)(2)]·8H(2)O, the Co(III) atom in the binuclear centrosymmetric anion is octa-hedrally surrounded by one N atom and three O atoms of the tetra-dentate nitrilo-triacetate ligand and two ?-hydroxide ligands. The crystal packing is controlled by C-H?O and O-H?O hydrogen-bonding inter-actions. The crystal employed in this study proved to be a two-component twin around (01).

SUBMITTER: Visser HG

PROVIDER: S-EPMC3009231 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Bis(tetra-phenyl-arsonium) di-μ-hy-droxido-bis-[(nitrilo-triacetato)-cobalt(III)] octa-hydrate.

Visser Hendrik G HG Clegg Jack K JK

Acta crystallographica. Section E, Structure reports online 20101013 Pt 11

In the title compound, (C(24)H(20)As)(2)[Co(2)(C(6)H(6)NO(6))(2)(OH)(2)]·8H(2)O, the Co(III) atom in the binuclear centrosymmetric anion is octa-hedrally surrounded by one N atom and three O atoms of the tetra-dentate nitrilo-triacetate ligand and two μ-hydroxide ligands. The crystal packing is controlled by C-H⋯O and O-H⋯O hydrogen-bonding inter-actions. The crystal employed in this study proved to be a two-component twin around (01). ...[more]

PMID: 21588834

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