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2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole.

ABSTRACT: The title compound, C(16)H(18)N(4)S(2), was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis-(bromo-meth-yl)-2,5-dimethyl-benzene. The mol-ecule is located on a crystallographic centre of inversion and therefore adopts a trans configuration with regards to the orientation of the two sulfur atoms. An inter-molecular N-H?N hydrogen bond forms layers of mol-ecules parallel to (03). The dihedral angle between the central and terminal rings is 174.8?(2)°.

SUBMITTER: Applewhite MJ

PROVIDER: S-EPMC3009242 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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2-({4-[(1H-Imidazol-2-ylsulfanyl)methyl]-2,5-dimethylbenzyl}sulfanyl)-1H-imidazole.

Applewhite Malcolm J MJ Potts Storm V SV

Acta crystallographica. Section E, Structure reports online 20101009 Pt 11

The title compound, C(16)H(18)N(4)S(2), was prepared by the substitution reaction of two equivalents of 2-mercaptoimidazole for every bromine substituent of 1,4-bis-(bromo-meth-yl)-2,5-dimethyl-benzene. The mol-ecule is located on a crystallographic centre of inversion and therefore adopts a trans configuration with regards to the orientation of the two sulfur atoms. An inter-molecular N-H⋯N hydrogen bond forms layers of mol-ecules parallel to (03). The dihedral angle between the central and ter ...[more]

PMID: 21588954

Similar Datasets

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Project description:In the title compound, C(15)H(11)N(3)S, the dihedral angle between the benzimidazole ring system and the benzene ring is 51.8?(2)°. The crystal structure exhibits inter-molecular N-H?N hydrogen bonds which lead to the formation of C(4) chains along the [001] direction.

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Project description:In the crystal of the title compound, C7H9N3O4, mol-ecules are linked by weak C-H⋯O hydrogen bonds into chains along the a-axis direction. The dihedral angle between the ring and the nitro group is 3.03 (6), while that between the ring and the acetate group is 85.01 (3)°.

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