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3,3-Dichloro-1-(chloro-meth-yl)indolin-2-one.

ABSTRACT: In the title compound, C(9)H(6)Cl(3)NO, the pyrrole ring is almost coplanar with the benzene ring [dihedral angle = 1.90?(9)°], while the Cl-C-N-C torsion angle is 98.78?(17)°. In the crystal, pairs of mol-ecules are inter-connected by pairs of Cl?Cl inter-actions [3.564?(5)?Å], forming dimers, which are further peripherally connected through inter-molecular C-H?O=C and ?-? inter-actions [centroid-centroid distances = 4.134?(7), 4.134?(6) and 4.238?(7)?Å], forming a two-dimensional network.

SUBMITTER: Wang Y

PROVIDER: S-EPMC3009249 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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3,3-Dichloro-1-(chloro-meth-yl)indolin-2-one.

Wang Yao Y Wan Chong-Qing CQ Zheng Tingting T Cao Sheng-Li SL

Acta crystallographica. Section E, Structure reports online 20101020 Pt 11

In the title compound, C(9)H(6)Cl(3)NO, the pyrrole ring is almost coplanar with the benzene ring [dihedral angle = 1.90 (9)°], while the Cl-C-N-C torsion angle is 98.78 (17)°. In the crystal, pairs of mol-ecules are inter-connected by pairs of Cl⋯Cl inter-actions [3.564 (5) Å], forming dimers, which are further peripherally connected through inter-molecular C-H⋯O=C and π-π inter-actions [centroid-centroid distances = 4.134 (7), 4.134 (6) and 4.238 (7) Å], forming a two-dimensional network. ...[more]

PMID: 21589042

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