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Poly[ethyl-enediammonium [tris-[?(3)-hydrogenphosphato(2-)]dicadmium] monohydrate].

ABSTRACT: The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2-), parallel to the ab plane. The edge-sharing CdO(6) octa-hedra form infinite chains running along the a axis and are linked by CdO(5) and PO(4) polyhedra. The ethyl-ene-diammonium cation and the water mol-ecule are located between two adjacent inorganic layers and ensure the cohesion of the structure via N-H?O and O-H?O hydrogen bonds.

SUBMITTER: Assani A

PROVIDER: S-EPMC3009259 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Poly[ethyl-enediammonium [tris-[μ(3)-hydrogenphosphato(2-)]dicadmium] monohydrate].

Assani Abderrazzak A Saadi Mohamed M El Ammari Lahcen L

Acta crystallographica. Section E, Structure reports online 20101002 Pt 11

The title compound, {(C(2)H(10)N(2))[Cd(2)(HPO(4))(3)]·H(2)O}(n), was synthesized under hydro-thermal conditions. The structure of this hybrid compound consists of CdO(6), CdO(5) and PO(4) polyhedra arranged so as to build an anionic inorganic layer, namely [Cd(2)(HPO(4))(3)](2-), parallel to the ab plane. The edge-sharing CdO(6) octa-hedra form infinite chains running along the a axis and are linked by CdO(5) and PO(4) polyhedra. The ethyl-ene-diammonium cation and the water mol-ecule are locat ...[more]

PMID: 21588799

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