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Di-?-chlorido-dichlorido-bis{8-[2-(di-methyl-amino)-ethyl-amino]-quinoline}dicadmium monohydrate.

ABSTRACT: The title complex, [Cd2Cl4(C13H17N3)2]·H2O, is centrosymmetic and contains two Cd(2+) ions bridged by two Cl(-) ions, leading to a strictly planar Cd2Cl2 core. Each Cd(2+) ion is further coordinated by an additional Cl(-) ion and three N atoms of a tridentate 8-[2-(di-methyl-amino)-ethyl-amino]-quinoline ligand in the form of a considerably distorted octa-hedron for the overall coordination sphere. A lattice water mol-ecule is located on a twofold rotation axis and links pairs of complexes through N-H?O and O-H?Cl hydrogen bonds.

SUBMITTER: Al-Sudani AR

PROVIDER: S-EPMC3884398 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-dichlorido-bis{8-[2-(di-methyl-amino)-ethyl-amino]-quinoline}dicadmium monohydrate.

Al-Sudani Abdul-Razak H AR Kariuki Benson M BM

Acta crystallographica. Section E, Structure reports online 20130814 Pt 9

The title complex, [Cd2Cl4(C13H17N3)2]·H2O, is centrosymmetic and contains two Cd(2+) ions bridged by two Cl(-) ions, leading to a strictly planar Cd2Cl2 core. Each Cd(2+) ion is further coordinated by an additional Cl(-) ion and three N atoms of a tridentate 8-[2-(di-methyl-amino)-ethyl-amino]-quinoline ligand in the form of a considerably distorted octa-hedron for the overall coordination sphere. A lattice water mol-ecule is located on a twofold rotation axis and links pairs of complexes throu ...[more]

PMID: 24426990

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