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Dichlorido{2-morpholino-N-[1-(2-pyri-dyl)ethyl-idene]ethanamine-?N,N',N''}cadmium.

ABSTRACT: In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is five-coordinate, with the N,N',N''-tridentate Schiff base ligand 2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine and two Cl atoms in a distorted square-pyramidal geometry. In the crystal structure, C-H?Cl hydrogen-bonding inter-actions connect the mol-ecules into a three-dimensional network.

SUBMITTER: Ikmal Hisham N

PROVIDER: S-EPMC3009368 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Dichlorido{2-morpholino-N-[1-(2-pyri-dyl)ethyl-idene]ethanamine-κN,N',N''}cadmium.

Ikmal Hisham Nurulazimah N Suleiman Gwaram Nura N Khaledi Hamid H Mohd Ali Hapipah H

Acta crystallographica. Section E, Structure reports online 20101030 Pt 11

In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is five-coordinate, with the N,N',N''-tridentate Schiff base ligand 2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine and two Cl atoms in a distorted square-pyramidal geometry. In the crystal structure, C-H⋯Cl hydrogen-bonding inter-actions connect the mol-ecules into a three-dimensional network. ...[more]

PMID: 21588887

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Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-?N,N',N''}manganese(II).

Project description:In the title compound, [MnCl(2)(C(13)H(19)N(3)O)], the Mn(II) ion is penta-coordinated in a distorted square-pyramidal geometry. The coordination environment is defined by the N,N',N''-tridentate Schiff base ligand and one Cl atom in the basal positions and one Cl atom in the apical position. In the crystal, inter-molecular C-H?Cl hydrogen bonds link the mol-ecules into a three-dimensional network. An intra-molecular C-H?Cl hydrogen bond is also observed.

| S-EPMC3050125 | biostudies-literature

Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-?N,N',N''}zinc(II).

Project description:In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H?Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H?Cl hydrogen-bonding and long range C-H?O and C-H?Cl inter-actions into a three-dimensional network.

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Dibromido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).

Project description:In the title complex, [ZnBr(2)(C(13)H(19)N(3)O)], the Zn(II) atom is five-coordinated by the three N-donor atoms of the Schiff base ligand and by two Br atoms in a distorted square-pyramidal geometry. The morpholine ring adopts a chair conformation.

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Di-μ-thio-cyanato-κN:S;κS:N-bis-({2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}(thio-cyanato-κN)cadmium).

Project description:In the title complex, [Cd(2)(NCS)(4)(C(13)H(19)N(3)O)(2)], the two Cd(II) ions are bridged by a pair of thio-cyanate N:S-bridging ligands around an inversion center. One terminal thio-cyanate N atom and one N,N',N''-tridentate Schiff base ligand complete a distorted CdN(5)S octa-hedral geometry about each Cd(II) atom. In the crystal, the Schiff base aromatic rings of adjacent mol-ecules are arranged above each other into infinite chains along the a axis with alternate centroid-centroid separations of 3.5299 (13) and 3.7857 (13) Å.

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{2-Morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-?N,N',N''}bis-(thio-cyanato-?N)copper(II).

Project description:In the title compound, [Cu(NCS)(2)(C(13)H(19)N(3)O)], the Cu(II) ion is five-coordinated by the N,N',N''-tridentate Schiff base and the N atoms of two isothio-cyanate ligands in a square-pyramidal geometry. In the crystal, C-H?N, C-H?O and C-H?S inter-actions link adjacent mol-ecules into layers parallel to the ac plane. A weak inter-molecular ?-? inter-action occurs between the aromatic rings with a centroid-centroid distance of 3.9412?(9)?Å.

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{2-Morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)zinc(II).

Project description:The asymmetric unit of the title compound, [Zn(NCS)(2)(C(13)H(19)N(3)O)], contains two crystallographically independent mol-ecules. In each mol-ecule, the Zn(II) ion is five-coordinated by the N,N',N"-tridentate Schiff base and the N atoms of two thio-cyanate ligands in a distorted square-pyramidal geometry. The two mol-ecules differ mainly in the deviations from the ideal geometry, with τ values of 0.14 and 0.33. In the crystal, inter-molecular C-H⋯S hydrogen bonds are observed. An intra-molecular C-H⋯N hydrogen bond occurs in one of the independent mol-ecules.

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Dichlorido{2-(morpholin-4-yl)-N-[1-(pyridin-2-yl)ethyl-idene]ethanamine-κN,N',N''}copper(II) monohydrate.

Project description:In the title compound, [CuCl(2)(C(13)H(19)N(3)O)]·H(2)O, the tridentate Schiff base ligand and the two Cl atoms complete a distorted square-pyramidal coordination geometry around the Cu(II) ion in which the three N atoms and one Cl atom are located in the basal plane and the other Cl atom is at the apical position. In the crystal, O-H⋯Cl hydrogen bonds link the complex mol-ecules and the uncoordinated water mol-ecules into infinite chains along the a axis. The chains are further connected into a three-dimensional network via C-H⋯O and C-H⋯Cl inter-actions.

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Dibromido{2-(morpholin-4-yl)-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}cadmium.

Project description:The Cd(II) ion in the title compound, [CdBr(2)(C(13)H(19)N(3)O)], is five-coordinated by the N,N',N''-tridentate Schiff base ligand and two Br atoms in a distorted square-pyramidal geometry. In the crystal, inter-molecular C-H⋯O and C-H⋯Br hydrogen bonds link adjacent mol-ecules into layers parallel to the ab plane. An intra-molecular C-H⋯Br inter-action is also observed.

| S-EPMC3052017 | biostudies-literature

Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri-dyl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)manganese(II).

Project description:In the title compound, [Mn(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Schiff base acts as an N,N',N"-tridentate ligand, forming two five-membered chelating rings with the Mn(II) atom. The distorted octa-hedral geometry around the metal atom is completed by two cis-positioned N-bound thio-cyanate ligands and one water mol-ecule. In the crystal, adjacent mol-ecules are linked through O-H⋯O, O-H⋯S and C-H⋯S hydrogen bonds into a three-dimensional supra-mol-ecular structure. An intra-molecular C-H⋯O hydrogen bond also occurs.

| S-EPMC3151779 | biostudies-literature

Aqua-{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}bis-(thio-cyanato-κN)cobalt(II).

Project description:In the title complex, [Co(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Co(II) ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thio-cyanate ligands and one water mol-ecule in a distorted octa-hedral geometry. Intra-molecular C-H⋯N and C-H⋯O hydrogen bonds occur. In the crystal, inter-molecular O-H⋯O, O-H⋯S, C-H⋯S and S⋯S [3.5546 (18) Å] inter-actions result in an infinite three-dimensional network.

| S-EPMC3051502 | biostudies-literature

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