(Z)-3-Diethyl-amino-6-({2-[(E)-4-(diethyl-amino)-2-hy-droxy-benzyl-idene-amino]-4,5-dimethyl-phen-yl}amino-methyl-idene)cyclo-hexa-2,4-dienone-5,5'-bis-(diethyl-amino)-2,2'-[4,5-dimethyl-o-phenyl-enebis(nitrilo-methyl-idyne)]diphenol.

ABSTRACT: The asymmetric unit of the title Schiff base compound, C(30)H(38)N(4)O(2), comprises two crystallographically independent mol-ecules, A and B. The structure is non-merohedrally twinned with a refined BASF ratio of 0.219?(6):0.701?(6). Mol-ecule B shows both phenol-imine and keto-amine tautomeric forms in a single structure. The dihedral angles between the central ring and the two outer rings are 5.9?(3) and 48.4?(3)° in mol-ecule A, and 48.3?(3) and 6.9?(3)° in mol-ecule B. Strong intra-molecular O-H?N and N-H?O hydrogen bonds generate S(6) ring motifs. The crystal structure is further stabilized by inter-molecular C-H?O, C-H?? and ?-? inter-actions [centroid-centroid distances = 3.870?(4)-3.871?(4)?Å].

SUBMITTER: Kargar H 

PROVIDER: S-EPMC3011455 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature