Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

4-[(9-Ethyl-9H-carbazol-3-yl)imino-meth-yl]phenol.

ABSTRACT: In the title compound, C(21)H(18)N(2)O, the dihedral angle between the phenol ring and the carbazole system is 39.34?(2)°. Inter-molecular O-H?N hydrogen bonds and C-H?? and ?-? inter-actions [centroid-centroid distances = 3.426?(2) and 3.768?(2)?Å] stabilize the crystal structure.

SUBMITTER: Lin S

PROVIDER: S-EPMC3011571 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

4-[(9-Ethyl-9H-carbazol-3-yl)imino-meth-yl]phenol.

Lin Songzhu S Jia Ruokun R Gao Xiaoli X Yu Haihui H Yuan Yanlin Y

Acta crystallographica. Section E, Structure reports online 20101117 Pt 12

In the title compound, C(21)H(18)N(2)O, the dihedral angle between the phenol ring and the carbazole system is 39.34 (2)°. Inter-molecular O-H⋯N hydrogen bonds and C-H⋯π and π-π inter-actions [centroid-centroid distances = 3.426 (2) and 3.768 (2) Å] stabilize the crystal structure. ...[more]

PMID: 21589488

Similar Datasets

2-[(4-Ethyl-phen-yl)imino-meth-yl]-3,5-dimethoxy-phenol.

Project description:The title compound, C(17)H(19)NO(3), adopts the phenol-imine tautomeric form, with a resonance-assisted O-H?N intra-molecular hydrogen bond [O?N = 2.551?(3)?Å]. The dihedral angle between the two benzene rings is 45.42?(7)°. The two meth-oxy groups are coplanar with the attached benzene ring [C-O-C-C torsion angles = -1.1?(5) and 3.2?(4)°].

| S-EPMC2968664 | biostudies-literature

(E)-4-Bromo-2-[(4-ethyl-phen-yl)imino-meth-yl]phenol.

Project description:In the title compound, C(15)H(14)BrNO, the dihedral angle between the two benzene rings is 43.99?(2)°. The mol-ecular conformation is influenced by an intra-molecular O-H?N hydrogen bond.

| S-EPMC2915047 | biostudies-literature

(E)-2-[(2-Ethyl-phen-yl)imino-meth-yl]-6-methoxy-phenol.

Project description:The mol-ecule of the title compound, C(16)H(17)NO(2), adopts the phenol-imine tautomeric form with a strong intra-molecular O-H?N hydrogen bond and an E conformation with respect to the azomethine C=N bond. The dihedral angle between the aromatic rings is 21.23?(9)°. The ethyl group is disordered over two orientations with occupancies of 0.598?(6) and 0.402?(6). In the crystal, the mol-ecules are linked into chains along the b axis by C-H?? inter-actions.

| S-EPMC2979675 | biostudies-literature

(E)-2-{[2-(2-Hy-droxy-ethyl-amino)-ethyl-imino]-meth-yl}phenol.

Project description:The asymmetric unit of the title compound, C(11)H(16)N(2)O(2), contains two independent conformational isomers which show intra-molecular aromatic-imine O-H⋯N hydrogen bonds. In the crystal, neighboring mol-ecules are linked through inter-molecular aliphatic-aliphatic O-H⋯N, aliphatic-aromatic N-H⋯O and C-H⋯O inter-actions into hydrogen-bonded layers parallel to the ab plane.

| S-EPMC3247587 | biostudies-literature

(4,9-Dimethyl-9H-carbazol-3-yl)meth-anol.

Project description:In the title compound, C15H15NO, the carbazole skeleton includes a methanol group at the 3-position. The indole ring system is almost planar [maximum deviation = 0.045 (2) Å]. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into zigzag chains along the b-axis direction. There are weak C-H⋯π inter-actions within the chains and linking neighbouring chains forming sheets lying parallel to (001).

| S-EPMC3998416 | biostudies-literature

(E)-4-Methyl-2-[(R)-1-phenyl-ethyl-imino-meth-yl]phenol.

Project description:In the title Schiff base, C(16)H(17)NO, the dihedral angle between the two aromatic rings is 63.59?(2)°. A strong intra-molecular O-H?N hydrogen bond is observed between the hydroxyl group and the imine N atom.

| S-EPMC2961494 | biostudies-literature

4-Phenyl-diazenyl-2-[(R)-(1-phenyl-ethyl)imino-meth-yl]phenol.

Project description:The title chiral photochromic Schiff base compound, C(21)H(19)N(3)O, was synthesized from (R)-1-phenyl-ethyl-amine and the salicylaldehyde of an azobenzene derivative. The mol-ecule corresponds to the phenol-imine tautomer, the C=N and N-C bond distances being 1.279 (3) and 1.477 (3) Å, respectively. An intra-molecular O-H⋯N hydrogen bond occurs. The diazenyl group adopts a trans form with an N=N distance of 1.243 (3) Å.

| S-EPMC2983984 | biostudies-literature

2-Bromo-4-chloro-6-[(1-phenyl-ethyl)-imino-meth-yl]phenol.

Project description:The title compound, C(15)H(13)BrClNO, is a Schiff base derived from the condensation of equimolar quanti-ties of 3-bromo-5-chloro-salicylaldehyde and 1-phenyl-ethanamine. The structure displays a trans configuration with respect to the imine C=N double bond. The N atom is also involved in an intra-molecular O-H-N hydrogen bond, which stabilizes the configuration of the compound.

| S-EPMC2959591 | biostudies-literature

4-Chloro-2-[(E)-2-(4-methoxy-phen-yl)ethyl-imino-meth-yl]phenol.

Project description:In the title Schiff base, C(16)H(16)ClNO(2), the 2-(4-methoxy-phen-yl)ethyl (CH(3)OC(6)H(4)CH(2)CH(2)-; r.m.s. deviation = 0.10 Å) and 4-chloro-2-(imino-meth-yl)phenol (N=CHC(6)H(3)ClOH; r.m.s. deviation = 0.01 Å) portions are both essentially planar, the two parts being inclined at an angle of 61.8 (1)°. The hydroxy group forms a hydrogen bond to the imino N atom.

| S-EPMC2977750 | biostudies-literature

(E)-3-(9-Ethyl-9H-carbazol-3-yl)-1-(2-meth-oxy-phen-yl)prop-2-en-1-one.

Project description:In the title mol-ecule, C24H21NO2, the dihedral angle between the carbazole ring system [with a maximum deviation of 0.052 (2) Å] and the benzene ring is 38.6 (1)°. In the crystal, weak bifurcated (C-H)2⋯O hydrogen bonds link the mol-ecules into chains along [100].

| S-EPMC3998340 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data