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(E)-2-[(2-Ethyl-phen-yl)imino-meth-yl]-6-methoxy-phenol.


ABSTRACT: The mol-ecule of the title compound, C(16)H(17)NO(2), adopts the phenol-imine tautomeric form with a strong intra-molecular O-H?N hydrogen bond and an E conformation with respect to the azomethine C=N bond. The dihedral angle between the aromatic rings is 21.23?(9)°. The ethyl group is disordered over two orientations with occupancies of 0.598?(6) and 0.402?(6). In the crystal, the mol-ecules are linked into chains along the b axis by C-H?? inter-actions.

SUBMITTER: Yaz?c? S 

PROVIDER: S-EPMC2979675 | biostudies-literature | 2010 Jan

REPOSITORIES: biostudies-literature

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(E)-2-[(2-Ethyl-phen-yl)imino-meth-yl]-6-methoxy-phenol.

Yazıcı Serap S   Albayrak Ciğdem C   Gümrükçüoğlu Ismail I   Senel Ismet I   Büyükgüngör Orhan O  

Acta crystallographica. Section E, Structure reports online 20100109 Pt 2


The mol-ecule of the title compound, C(16)H(17)NO(2), adopts the phenol-imine tautomeric form with a strong intra-molecular O-H⋯N hydrogen bond and an E conformation with respect to the azomethine C=N bond. The dihedral angle between the aromatic rings is 21.23 (9)°. The ethyl group is disordered over two orientations with occupancies of 0.598 (6) and 0.402 (6). In the crystal, the mol-ecules are linked into chains along the b axis by C-H⋯π inter-actions. ...[more]

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