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?-Nd(2)Mo(4)O(15).

ABSTRACT: The title compound, dineodymium(III) tetra-molybdate(VI), has been prepared by a flux technique and is the second polymorph of composition Nd(2)Mo(4)O(15). The crystal structure is isotypic with those of Ce(2)Mo(4)O(15) and Pr(2)Mo(4)O(15). It features a three-dimensional network composed of distorted edge- and corner-sharing NdO(7) polyhedra, NdO(8) polyhedra, MoO(4) tetra-hedra and MoO(6) octa-hedra.

SUBMITTER: Zhao D

PROVIDER: S-EPMC3011581 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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β-Nd(2)Mo(4)O(15).

Zhao Dan D Li Fei-Fei FF Yao Yu-Ming YM Huan Chang-An CA Zhao En-Xiao EX

Acta crystallographica. Section E, Structure reports online 20101127 Pt 12

The title compound, dineodymium(III) tetra-molybdate(VI), has been prepared by a flux technique and is the second polymorph of composition Nd(2)Mo(4)O(15). The crystal structure is isotypic with those of Ce(2)Mo(4)O(15) and Pr(2)Mo(4)O(15). It features a three-dimensional network composed of distorted edge- and corner-sharing NdO(7) polyhedra, NdO(8) polyhedra, MoO(4) tetra-hedra and MoO(6) octa-hedra. ...[more]

PMID: 21589208

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