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Nd(2)(WO(4))(3).

ABSTRACT: The title compound, dineodymium(III) tris-[tungstate(VI)], is a member of the Eu(2)(WO(4))(3) structure family and crystallizes isotypically with other rare earth tungstates and molybdates of this formula type. The structure is a derivative of the scheelite (CaWO(4)) structure and can be considered as an ordered defect variant with a threefold scheelite supercell and one rare earth (RE) site unoccupied. The Nd(3+) cations are coordinated by eight O atoms in form of a distorted bicapped trigonal prism. The two unique W cations are tetra-hedrally surrounded by O atoms. One WO(4) tetra-hedron has 2 symmetry and is relatively undistorted whereas the other tetra-hedron differs considerably from an ideal geometry. This is caused by an additional remote O atom at a distance of 2.149?(4)?Å. The resulting WO(4 + 1) polyhedra form W(2)O(8) dimers through edge-sharing. Together with the WO(4) and NdO(8) units, the three-dimensional set-up is accomplished.

SUBMITTER: Weil M

PROVIDER: S-EPMC2969527 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Nd(2)(WO(4))(3).

Weil Matthias M Stöger Berthold B Aleksandrov Lyubomir L

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

The title compound, dineodymium(III) tris-[tungstate(VI)], is a member of the Eu(2)(WO(4))(3) structure family and crystallizes isotypically with other rare earth tungstates and molybdates of this formula type. The structure is a derivative of the scheelite (CaWO(4)) structure and can be considered as an ordered defect variant with a threefold scheelite supercell and one rare earth (RE) site unoccupied. The Nd(3+) cations are coordinated by eight O atoms in form of a distorted bicapped trigonal ...[more]

PMID: 21582980

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