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(2,2'-Biquinoline-?N,N')dibromido-zinc(II).

ABSTRACT: In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 2,2'-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak inter-molecular C-H?Br hydrogen bonds and extensive inter-molecular ?-? contacts between the pyridine and benzene rings [centroid-centroid distances = 3.775?(4), 3.748?(4), 3.735?(4), 3.538?(4), 3.678?(4) and 3.513?(4)?Å].

SUBMITTER: Saravani H

PROVIDER: S-EPMC3011677 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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(2,2'-Biquinoline-κN,N')dibromido-zinc(II).

Saravani Hamideh H Rezvani Ali Reza AR Akbarzadeh Torbati Niloufar N

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12

In the title compound, [ZnBr(2)(C(18)H(12)N(2))], the Zn(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 2,2'-biquinoline ligand and two terminal Br atoms. The crystal packing is stabilized by weak inter-molecular C-H⋯Br hydrogen bonds and extensive inter-molecular π-π contacts between the pyridine and benzene rings [centroid-centroid distances = 3.775 (4), 3.748 (4), 3.735 (4), 3.538 (4), 3.678 (4) and 3.513 (4) Å]. ...[more]

PMID: 21589297

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