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(2,2'-Bipyridine-?N,N')dibromido-palladium(II) dichloro-methane solvate.

ABSTRACT: In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2'-bipyridine ligand and two bromide ions. The compound displays intra-molecular C-H?Br hydrogen bonds and pairs of complex mol-ecules are assembled by inter-molecular C-H?Br hydrogen bonds. These pairs are connected by additional C-H?Br hydrogen bonds, forming a layer structure extending parallel to (011). Inter-molecular ?-? inter-actions between the pyridine rings of the ligand are also present, the shortest centroid-centroid distance being 4.090?(9)?Å.

SUBMITTER: Kim NH

PROVIDER: S-EPMC2971059 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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(2,2'-Bipyridine-κN,N')dibromido-palladium(II) dichloro-methane solvate.

Kim Nam-Ho NH Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20091003 Pt 11

In the title compound, [PdBr(2)(C(10)H(8)N(2))]·CH(2)Cl(2), the Pd(2+) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2'-bipyridine ligand and two bromide ions. The compound displays intra-molecular C-H⋯Br hydrogen bonds and pairs of complex mol-ecules are assembled by inter-molecular C-H⋯Br hydrogen bonds. These pairs are connected by additional C-H⋯Br hydrogen bonds, forming a layer structure extending parallel to (011). Inter-molecu ...[more]

PMID: 21578060

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Redetermination of (2,2'-bipyridine-?N,N')dichlorido-palladium(II) dichloro-methane solvate.

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