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Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization.

ABSTRACT: The first rhodium-catalyzed arylation of imines proceeding via C-H bond functionalization is reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl-branched N-Boc-amines are formed, and a wide range of functionality is compatible with the reaction.

SUBMITTER: Tsai AS 

PROVIDER: S-EPMC3045530 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization.

Tsai Andy S AS   Tauchert Michael E ME   Bergman Robert G RG   Ellman Jonathan A JA  

Journal of the American Chemical Society 20110104 5

The first rhodium-catalyzed arylation of imines proceeding via C-H bond functionalization is reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl-branched N-Boc-amines are formed, and a wide range of functionality is compatible with the reaction. ...[more]

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