Ontology highlight
ABSTRACT:
SUBMITTER: Izgu EC
PROVIDER: S-EPMC3045753 | biostudies-literature | 2011 Feb
REPOSITORIES: biostudies-literature
Izgu Enver Cagri EC Burns Aaron C AC Hoye Thomas R TR
Organic letters 20110118 4
Various functionalized steroidal side chains were conveniently accessed by a modified Julia olefination strategy using a common sulfone donor and an appropriate α-branched aldehyde acceptor. For the coupling of these hindered classes of reaction partners (and in contrast to typically observed trends), the benzothiazolyl(BT)-sulfone anion gave superior outcomes compared to the phenyltetrazolyl(PT)-sulfone anion. ...[more]