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Bis(?-4-amino-3,5-dimethyl-4H-1,2,4-triazole)bis-[diiodidozinc(II)].

ABSTRACT: In the title compound, [Zn(2)I(4)(C(4)H(8)N(4))(2)], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry by two N atoms from the triazole rings of two 4-amino-3,5-dimethyl-4H-1,2,4-triazole (admt) ligands and two iodide ligands. Doubly bridging admt ligands connect two Zn(II) atoms, forming a centrosymmetric dimer. Weak N-H?I and C-H?I hydrogen bonds play an important role in the inter-molecular packing.

SUBMITTER: Zhang R 

PROVIDER: S-EPMC3050150 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Bis(μ-4-amino-3,5-dimethyl-4H-1,2,4-triazole)bis-[diiodidozinc(II)].

Zhang Rongxian R   Chen Qiuyun Q   Yang Xiaofei X   Wu Xiangyang X  

Acta crystallographica. Section E, Structure reports online 20101204 Pt 1

In the title compound, [Zn(2)I(4)(C(4)H(8)N(4))(2)], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry by two N atoms from the triazole rings of two 4-amino-3,5-dimethyl-4H-1,2,4-triazole (admt) ligands and two iodide ligands. Doubly bridging admt ligands connect two Zn(II) atoms, forming a centrosymmetric dimer. Weak N-H⋯I and C-H⋯I hydrogen bonds play an important role in the inter-molecular packing. ...[more]

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