Unknown

Dataset Information

0

2-Amino-4-methyl-pyridinium 6-carb-oxy-pyridine-2-carboxyl-ate methanol monosolvate.


ABSTRACT: In the title solvated molecular salt, C(6)H(9)N(2) (+)·C(7)H(4)NO(4) (-)·CH(4)O, the pyridine N atom of 2-amino-4-methyl-pyridine is protonated and one carboxyl group of pyridine-2,6-dicarb-oxy-lic acid is deprotonated. The dihedral angles between the -CO(2) and -COH groups and the pyridine ring are 0.65?(13) and 7.4°. The crystal packing is stabilized by inter-molecular N-H?O, O-H?O and weak C-H?O hydrogen bonds.

SUBMITTER: Aghabozorg H 

PROVIDER: S-EPMC3050251 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

altmetric image

Publications

2-Amino-4-methyl-pyridinium 6-carb-oxy-pyridine-2-carboxyl-ate methanol monosolvate.

Aghabozorg Hossein H   Mofidi Rouchi Azadeh A   Mirzaei Masoud M   Notash Behrouz B  

Acta crystallographica. Section E, Structure reports online 20101208 Pt 1


In the title solvated molecular salt, C(6)H(9)N(2) (+)·C(7)H(4)NO(4) (-)·CH(4)O, the pyridine N atom of 2-amino-4-methyl-pyridine is protonated and one carboxyl group of pyridine-2,6-dicarb-oxy-lic acid is deprotonated. The dihedral angles between the -CO(2) and -COH groups and the pyridine ring are 0.65 (13) and 7.4°. The crystal packing is stabilized by inter-molecular N-H⋯O, O-H⋯O and weak C-H⋯O hydrogen bonds. ...[more]

Similar Datasets

| S-EPMC3011762 | biostudies-literature
| S-EPMC3238974 | biostudies-literature
| S-EPMC3006734 | biostudies-literature
| S-EPMC3212294 | biostudies-literature
| S-EPMC5458309 | biostudies-literature
| S-EPMC3770389 | biostudies-literature
| S-EPMC3007404 | biostudies-literature
| S-EPMC3515249 | biostudies-literature
| S-EPMC3254532 | biostudies-literature
| S-EPMC3297954 | biostudies-literature