Dataset Information
Crystal structure of 3-amino-pyridinium 1'-carb-oxy-ferrocene-1-carboxyl-ate.
Ontology highlight
ABSTRACT:
SUBMITTER: Medved'ko AV
PROVIDER: S-EPMC5458309 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
Publications
Crystal structure of 3-amino-pyridinium 1'-carb-oxy-ferrocene-1-carboxyl-ate.
Acta crystallographica. Section E, Crystallographic communications 20170516 Pt 6
The structure of the title salt, (C<sub>5</sub>H<sub>7</sub>N<sub>2</sub>)[Fe(C<sub>6</sub>H<sub>4</sub>O<sub>2</sub>)(C<sub>6</sub>H<sub>5</sub>O<sub>2</sub>)], consists of 3-amino-pyridinium cations and 1'-carb-oxy-ferrocene-1-carboxyl-ate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe-C distances in the range 2.0270 (15)-2.0568 (17) Å. The anion possesses an eclipsed conformation, with the torsion angle φ (C<sub>subst</sub>-Cp<sub>cent</sub>-Cp<sub ...[more]