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(3S)-2-Benzyl-3-carb-oxy-1,2,3,4-tetra-hydro-isoquinolinium chloride monohydrate.

ABSTRACT: In the title compound, C(17)H(18)NO(2) (+)·Cl(-)·H(2)O, a precursor to novel asymmetric catalysts, the N-containing six-membered ring of the tetra-hydro-quinolinium unit assumes a half-boat conformation. In the crystal, inter-molecular O-H?O, O-H?Cl, N-H?Cl and C-H?O hydrogen bonds and C-H?? inter-actions link the mol-ecules into a three-dimensional network.

SUBMITTER: Naicker T

PROVIDER: S-EPMC3050278 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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(3S)-2-Benzyl-3-carb-oxy-1,2,3,4-tetra-hydro-isoquinolinium chloride monohydrate.

Naicker Tricia T Govender Thavendran T Kruger Hendrik G HG Maguire Glenn E M GE

Acta crystallographica. Section E, Structure reports online 20101224 Pt 1

In the title compound, C(17)H(18)NO(2) (+)·Cl(-)·H(2)O, a precursor to novel asymmetric catalysts, the N-containing six-membered ring of the tetra-hydro-quinolinium unit assumes a half-boat conformation. In the crystal, inter-molecular O-H⋯O, O-H⋯Cl, N-H⋯Cl and C-H⋯O hydrogen bonds and C-H⋯π inter-actions link the mol-ecules into a three-dimensional network. ...[more]

PMID: 21522727

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