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Diiodidobis(triphenyl-phosphine oxide)cadmium.

ABSTRACT: In the title compound, [CdI(2){(C(6)H(5))(3)PO}(2)], the Cd(II) atom is ligated by two I atoms and two O atoms from two triphenyl-phosphine oxide ligands in a disorted tetra-hedral arrangement. While the O-Cd-I angles vary from 106.67?(7) to 111.23?(7)°, the O-Cd-O angle is 88.60?(10)° and the I-Cd-I angle angle is 125.47?(2)°. The crystal structure is stabilized by van der Waals forces only.

SUBMITTER: Shanthakumari R 

PROVIDER: S-EPMC3050319 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Diiodidobis(triphenyl-phosphine oxide)cadmium.

Shanthakumari R R   Hema R R   Ramamurthy K K   Stoeckli-Evans Helen H  

Acta crystallographica. Section E, Structure reports online 20101224 Pt 1

In the title compound, [CdI(2){(C(6)H(5))(3)PO}(2)], the Cd(II) atom is ligated by two I atoms and two O atoms from two triphenyl-phosphine oxide ligands in a disorted tetra-hedral arrangement. While the O-Cd-I angles vary from 106.67 (7) to 111.23 (7)°, the O-Cd-O angle is 88.60 (10)° and the I-Cd-I angle angle is 125.47 (2)°. The crystal structure is stabilized by van der Waals forces only. ...[more]

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