Unknown

Dataset Information

0

Tris(thio-cyanato-?N)tris-(triphenyl-phosphine oxide-?O)europium(III)-(nitrato-?(2) O,O')bis-(thio-cyanato-?N)tris-(triphenyl-phosphine oxide-?O)europium(III) (1/1).

ABSTRACT: The title co-crystal, [Eu(NCS)3(C18H15OP)3][Eu(NCS)2(NO3)(C18H15OP)3], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu(3+) ion. As a result, the nitrate-containing mol-ecule contains disorder of its bidentate nitrate and two N-bound thio-cyanate anions, while the [Eu(NCS)3(OPPh3)3] complex is fully ordered. There is a weak ?-? stacking inter-action between the phenyl rings of the two mol-ecules [centroid-centroid distance = 4.138?(4)?Å].

SUBMITTER: Thames AT 

PROVIDER: S-EPMC3588774 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tris(thio-cyanato-κN)tris-(triphenyl-phosphine oxide-κO)europium(III)-(nitrato-κ(2) O,O')bis-(thio-cyanato-κN)tris-(triphenyl-phosphine oxide-κO)europium(III) (1/1).

Thames Anthony T AT   White Frankie D FD   Pham Lam N LN   Xiang Kang Rui KR   Sykora Richard E RE  

Acta crystallographica. Section E, Structure reports online 20121124 Pt 12

The title co-crystal, [Eu(NCS)3(C18H15OP)3][Eu(NCS)2(NO3)(C18H15OP)3], contains two distinct neutral complexes. Each complex has threefold symmetry about its central Eu(3+) ion. As a result, the nitrate-containing mol-ecule contains disorder of its bidentate nitrate and two N-bound thio-cyanate anions, while the [Eu(NCS)3(OPPh3)3] complex is fully ordered. There is a weak π-π stacking inter-action between the phenyl rings of the two mol-ecules [centroid-centroid distance = 4.138 (4) Å]. ...[more]

Similar Datasets

Unknown Tris(thio-cyanato-?N)tris-(triphenyl-phosphine oxide-?O)terbium(III).
| S-EPMC3588775 | biostudies-literature
Unknown Tris{N-[bis-(dimethyl-amino)phosphino-yl]-2,2,2-trichloro-acetamido}(triphenyl-phosphine oxide)holmium(III).
| S-EPMC2979613 | biostudies-literature
Unknown Tris{2-meth-oxy-6-[(4-methyl-phen-yl)iminiometh-yl]phenolate-?O,O'}tris-(thio-cyanato-?N)europium(III).
| S-EPMC2972108 | biostudies-literature
Unknown Tris(tetra-butyl-ammonium) tris-(nitrato-?O,O')tetra-kis-(thio-cyanato-?N)thorium(IV).
| S-EPMC3100005 | biostudies-literature
Unknown Bis(2,3,5-triphenyl-tetra-zolium) tetra-thio-cyanato-cobaltate(II).
| S-EPMC2970988 | biostudies-literature
Unknown Iodido(N-phenyl-thio-urea)bis-(triphenyl-phosphine)copper(I).
| S-EPMC2961665 | biostudies-literature
Unknown Di-?-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate.
| S-EPMC2984055 | biostudies-literature
Unknown Bis(acetyl-acetonato)oxido(triphenyl-phosphine oxide)vanadium(IV).
| S-EPMC2915097 | biostudies-literature
Unknown cis-Bis(nitrato-?O,O')bis-(triethyl-phosphine oxide-?O)nickel(II).
| S-EPMC2969723 | biostudies-literature
Unknown Tris[3,5-bis-(trifluoro-meth-yl)phen-yl]phosphine oxide.
| S-EPMC2977759 | biostudies-literature