Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(2,2'-bipyridyl-?N,N')(sulfato-?O,O')cobalt(II) ethane-1,2-diol monosolvate.

ABSTRACT: The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa-hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C-C bond of the ethane-diol mol-ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O-H?O hydrogen bonds.

SUBMITTER: Zhong KL

PROVIDER: S-EPMC3050350 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(2,2'-bipyridyl-κN,N')(sulfato-κO,O')cobalt(II) ethane-1,2-diol monosolvate.

Zhong Kai-Long KL Pan Xian-Xiao XX Cao Guo-Qing GQ Chen Lin L

Acta crystallographica. Section E, Structure reports online 20101208 Pt 1

The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa-hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C-C bond of the ethane-diol mol-ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O-H⋯O hydrogen bonds. ...[more]

PMID: 21522564

Similar Datasets

Bis(2,2'-bipyridyl-κN,N')(sulfato-κO,O')zinc(II) ethane-1,2-diol solvate.

Project description:The title compound, [Zn(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), is a six-coordinate zinc(II) complex with a distorted octa-hedral coordination geometry. The Zn(II) atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2'-bipyridine ligands. The Zn-N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn-O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are connected by inter-molecular O-H⋯O hydrogen bonding, which leads to additional stabilization of the structure.

| S-EPMC2979970 | biostudies-literature

Bis(1,10-phenanthroline-κN,N')(sulfato-O)copper(II) ethane-1,2-diol monosolvate.

Project description:In the title compound, [Cu(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the Cu(II) ion is five-coordinated in a distorted square-pyramidal manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate anion. The four N atoms comprise a square and the one O atom the apex of a square pyramid. The two chelating N(2)C(2) groups are oriented at 71.1 (2)°. In the crystal, the components are connected by inter-molecular O-H⋯O hydrogen bonding. The presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model.

| S-EPMC3200916 | biostudies-literature

Bis(1,10-phenanthroline-?(2) N,N')(sulfato-?(2) O,O')cobalt(II) propane-1,2-diol monosolvate.

Project description:In the title compound, [Co(SO4)(C12H8N2)2]·C3H8O2, the Co(II) atom (site symmetry 2) has a distorted octa-hedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O'-bidentate sulfate ligand, in which the S atom has site symmetry 2. The dihedral angle between the two chelating N2C2 groups is 84.46?(15)°. The complex and solvent mol-ecules are connected through O-H?O hydrogen bonds. The solvent mol-ecule is equally disordered over two positions and is also located on a twofold axis.

| S-EPMC3588351 | biostudies-literature

Bis(1,10-phenanthroline-?N,N')(sulfato-?O,O')cobalt(II) butane-2,3-diol monosolvate.

Project description:In the title compound, [Co(SO(4))(C(12)H(8)N(2))(2)]·C(4)H(10)O(2), the Co(2+) ion has a distorted octa-hedral coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O'-bidentate sulfate anion. The dihedral angle between the two chelating N(2)C(2) groups is 83.48?(1)°. The Co(2+) ion, the S atom and the mid-point of the central C-C bond of the butane-2,3-diol solvent mol-ecule are situated on twofold rotation axes. The mol-ecules of the complex and the solvent mol-ecules are held together by pairs of symmetry-related O-H?O hydrogen bonds with the uncoordinated O atoms of the sulfate ions as acceptors. The solvent mol-ecule is disordered over two sets of sites with site occupancies of 0.40 and 0.60.

| S-EPMC3100011 | biostudies-literature

Bis(1,10-phenanthroline-?N,N')(sulfato-?O,O')nickel(II) ethane-1,2-diol solvate.

Project description:In the title compound, [Ni(SO(4))(C(12)H(8)N(2))(2)]·C(2)H(6)O(2), the coordination polyhedron around the Ni(2+) ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni(2+) ion lies on a special position of site symmetry 2. Inter-molecular O-H?O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy.

| S-EPMC2977342 | biostudies-literature

Bis(1,10-phenanthroline-?(2) N,N')(sulfato-?O)zinc(II) propane-1,2-diol monosolvate.

Project description:In the title compound, [Zn(SO4)(C12H8N2)2]·C3H8O2, the Zn(II) ion is in a distorted square-pyramidal coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and one O atom from a monodentate sulfate ligand. The Zn(II) ion lies on a twofold rotation axis. The sulfate ligand and propane-1,2-diol mol-ecules are disordered across the twofold rotation axis. The dihedral angle between the two chelating N2C2 groups is 83.26?(13)°. In the crystal, the complex mol-ecule and the propane-1,2-diol mol-ecule are connected through a pair of O-H?O hydrogen bonds.

| S-EPMC3790364 | biostudies-literature

Poly[diaqua-bis-(?-4,4'-bipyridine-?(2) N:N')bis-(ethane-1,2-diol-?O)bis(?-sulfato-?(2) O:O')dicobalt(II)].

Project description:In the title compound, [Co2(SO4)2(C10H8N2)2(C2H6O2)2(H2O)2] n , there are two crystallographically independent Co(II) ions, each of which lies on a twofold rotation axis and has a slightly distorted octa-hedral environment. One Co(II) ion is coordinated by two N atoms from two bridging 4,4'-bipyridine (4,4'-bipy) ligands, two O atoms from two sulfate ions and two O atoms from aqua ligands. The second Co(II) ion is similar but with ethane-1,2-diol ligands in place of water mol-ecules. The sulfate anions act as bridging ligands to link two adjacent Co(II) ions together, leading to the formation of linear ?Co1Co2Co1Co2?chains along the a axis. Adjacent chains are further bridged by 4,4'-bipy ligands, which are also located on the twofold rotation axis, resulting in a two-dimensional layered polymer extending parallel to (001). In the crystal, the layers are linked by extensive O-H?O hydrogen-bonding inter-actions involving the O atoms of the water mol-ecules and ethane-1,2-diol mol-ecules, resulting in a three-dimensional supra-molecular network.

| S-EPMC3629485 | biostudies-literature

Bis(4-chloro-pyridine){2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}cobalt(III) perchlorate methanol monosolvate.

Project description:In the title complex, [Co(C(16)H(14)N(2)O(2))(C(5)H(4)ClN)(2)]ClO(4)·CH(3)OH, the Co(III) ion is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment with the two 4-chloro-pyridine ligands in a trans arrangement.

| S-EPMC3011786 | biostudies-literature

Bis(2,2'-bipyridyl dioxide-?N,N')bis-(tricyano-methanido)cobalt(II) dihydrate.

Project description:In the title compound, [Co(C(4)N(3))(2)(C(10)H(8)N(2)O(2))]·2H(2)O, a novel tricyano-methanide complex, the Co(II) atom is located on an inversion center and has a distorted octa-hedral coordination with two 2,2'-bipyridyl dioxide (dpdo) mol-ecules and two trans tricyano-methanide (tcm) anions. The equatorial plane is formed by the four O atoms of the two chelating dpdo ligands, with one N atom of each of the two tcm ligands occupying an apical position. There is a disordered solvent water mol-ecule in the asymmetric unit (occupancy ratio 0.63:0.37). These water mol-ecules result in the formation of O-H?O and O-H?N hydrogen bonds, building a layer parallel to (100). The layers are linked by C-H?N hydrogen-bonding inter-actions, leading to a three-dimensional network.

| S-EPMC2979455 | biostudies-literature

Bis(1,10-phenanthroline-?(2) N,N')(sulfato-O)copper(II) propane-1,3-diol monosolvate.

Project description:In the title compound, [Cu(SO4)(C12H8N2)2]·C3H8O2, the Cu(II) ion is bonded to two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate ligand in a distorted square-based pyramidal arrangement, with the O atom in a basal site. The two chelating N2C2 groups subtend a dihedral angle of 71.10?(15)°. In the crystal, the solvent mol-ecule forms two O-H?O hydrogen bonds to its adjacent complex mol-ecule. The chosen crystal was found to be a racemic twin; the presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model and high R and wR values.

| S-EPMC3588794 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data