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Bis(2,2'-bipyridyl-?N,N')(sulfato-?O,O')cobalt(II) ethane-1,2-diol monosolvate.

ABSTRACT: The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa-hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C-C bond of the ethane-diol mol-ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O-H?O hydrogen bonds.

SUBMITTER: Zhong KL

PROVIDER: S-EPMC3050350 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Bis(2,2'-bipyridyl-κN,N')(sulfato-κO,O')cobalt(II) ethane-1,2-diol monosolvate.

Zhong Kai-Long KL Pan Xian-Xiao XX Cao Guo-Qing GQ Chen Lin L

Acta crystallographica. Section E, Structure reports online 20101208 Pt 1

The title compound, [Co(SO(4))(C(10)H(8)N(2))(2)]·C(2)H(6)O(2), has the Co(2+) ion in a distorted octa-hedral CoN(4)O(2) coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C-C bond of the ethane-diol mol-ecule. In the crystal, the [CoSO(4)(C(10)H(8)N(2))(2)] and C(2)H(6)O(2) units are held together by a pair of O-H⋯O hydrogen bonds. ...[more]

PMID: 21522564

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