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(4,7-Diphenyl-1,10-phenanthroline-?N,N')dimethyl-bis-(thio-cyanato-?N)tin(IV).

ABSTRACT: In the title compound, [Sn(CH(3))(2)(NSC)(2)(C(24)H(16)N(2))], a 1:1 adduct of dimethyl-tin diisothio-cyanate with 4,7-diphenyl-1,10-phenanthroline, the Sn(IV) atom shows a slightly distorted octa-hedral SnC(2)N(4) coordination. The methyl groups are trans to each other in the octa-hedron surrounding the metal atom [C-Sn-C = 176.61?(12)°].

SUBMITTER: Najafi E

PROVIDER: S-EPMC3051511 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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(4,7-Diphenyl-1,10-phenanthroline-κN,N')dimethyl-bis-(thio-cyanato-κN)tin(IV).

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the title compound, [Sn(CH(3))(2)(NSC)(2)(C(24)H(16)N(2))], a 1:1 adduct of dimethyl-tin diisothio-cyanate with 4,7-diphenyl-1,10-phenanthroline, the Sn(IV) atom shows a slightly distorted octa-hedral SnC(2)N(4) coordination. The methyl groups are trans to each other in the octa-hedron surrounding the metal atom [C-Sn-C = 176.61 (12)°]. ...[more]

PMID: 21522899

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