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Catena-Poly[[dimethyl-bis-(thio-cyanato-?N)tin(IV)]-?-(4,4'-bipyridine-?N:N')].


ABSTRACT: The title dimethyl-tin diisothio-cyanate adduct of 4,4'-bipyridine, [Sn(CH(3))(2)(NCS)(2)(C(10)H(8)N(2))](n), adopts a chain motif in which the N-heterocycle functions as a bridge to adjacent all-trans octa-hedrally coordinated tin atoms. The Sn(IV) atom lies on a special position of 2/m site symmetry, the methyl C atom on a special position of 2 site symmetry, and the thio-cyanate and 4,4'-bipyridine on a special position of m site symmetry.

SUBMITTER: Najafi E 

PROVIDER: S-EPMC3052023 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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catena-Poly[[dimethyl-bis-(thio-cyanato-κN)tin(IV)]-μ-(4,4'-bipyridine-κN:N')].

Najafi Ezzatollah E   Amini Mostafa M MM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20110219 Pt 3


The title dimethyl-tin diisothio-cyanate adduct of 4,4'-bipyridine, [Sn(CH(3))(2)(NCS)(2)(C(10)H(8)N(2))](n), adopts a chain motif in which the N-heterocycle functions as a bridge to adjacent all-trans octa-hedrally coordinated tin atoms. The Sn(IV) atom lies on a special position of 2/m site symmetry, the methyl C atom on a special position of 2 site symmetry, and the thio-cyanate and 4,4'-bipyridine on a special position of m site symmetry. ...[more]

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