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2-(4-Meth-oxy-phen-yl)-4H-1,3,2-benzoxathia-phosphinine 2-sulfide.

ABSTRACT: The asymmetric unit of the title compound, C(14)H(13)O(2)PS(2), contains two crystallographically independent mol-ecules, which differ in the conformation of the 1,3,2-benzoxathia-phosphinine moieties (screw boat in the first mol-ecule and envelope in the second mol-ecule). In the crystal, neither classical nor non-classical hydrogen bonds are found. Weak inter-actions (about 2.9-3.0?Å) between the lone pair of the terminal S atoms with H atoms occur. This compound was further characterized by (1)H NMR and IR spectroscopy.

SUBMITTER: Osyanin VA

PROVIDER: S-EPMC3051562 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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2-(4-Meth-oxy-phen-yl)-4H-1,3,2-benzoxathia-phosphinine 2-sulfide.

Osyanin Vitaly A VA Ivleva Elena A EA Rybakov Victor B VB Klimochkin Yurij N YN

Acta crystallographica. Section E, Structure reports online 20110115 Pt 2

The asymmetric unit of the title compound, C(14)H(13)O(2)PS(2), contains two crystallographically independent mol-ecules, which differ in the conformation of the 1,3,2-benzoxathia-phosphinine moieties (screw boat in the first mol-ecule and envelope in the second mol-ecule). In the crystal, neither classical nor non-classical hydrogen bonds are found. Weak inter-actions (about 2.9-3.0 Å) between the lone pair of the terminal S atoms with H atoms occur. This compound was further characterized by ( ...[more]

PMID: 21523063

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