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Diaqua-(6-bromo-picolinato-?N,O)(nitrato-?O,O)copper(II).

ABSTRACT: In the monomeric title complex, [Cu(C(6)H(3)BrNO(2))(NO(3))(H(2)O)(2)], the Cu(II) ion is coordinated by a bidentate 6-bromo-picolinate ion, one nitrate ion and two water mol-ecules in a geometry inter-mediate between five- and six-coordinate. Conventional O-H?O hydrogen bonds link the complex mol-ecules, forming layers parallel to the ab plane.

SUBMITTER: Silva JA

PROVIDER: S-EPMC3051566 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Diaqua-(6-bromo-picolinato-κN,O)(nitrato-κO,O)copper(II).

Silva Joana A JA Pereira Magalhães Ana A Ramos Silva Manuela M Sobral Abílio J F N AJ Pereira Laura C J LC

Acta crystallographica. Section E, Structure reports online 20110112 Pt 2

In the monomeric title complex, [Cu(C(6)H(3)BrNO(2))(NO(3))(H(2)O)(2)], the Cu(II) ion is coordinated by a bidentate 6-bromo-picolinate ion, one nitrate ion and two water mol-ecules in a geometry inter-mediate between five- and six-coordinate. Conventional O-H⋯O hydrogen bonds link the complex mol-ecules, forming layers parallel to the ab plane. ...[more]

PMID: 21522841

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