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6-Cyclo-hexyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl(N?Bi) trifluoro-methane-sulfonate.

ABSTRACT: In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal-bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo-hexyl group is disordered over two orientations with site-occupancy factors of 0.600?(14) and 0.400?(14).

SUBMITTER: Tan N

PROVIDER: S-EPMC3051572 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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6-Cyclo-hexyl-6,7-dihydro-dibenzo[c,f][1,5]aza-bis-mocin-12(5H)-yl(N→Bi) trifluoro-methane-sulfonate.

Tan Nianyuan N Zhang Xiaowen X

Acta crystallographica. Section E, Structure reports online 20110122 Pt 2

In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal-bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo-hexyl group is disordered over two orientations with site-occupancy factors of 0.600 (14) and 0.400 (14). ...[more]

PMID: 21522906

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