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12-Chloro-6-cyclo-hexyl-5,6,7,12-tetra-hydro-dibenzo[c,f][1,5]aza-stibocine.

ABSTRACT: In the title organometallic complex, [Sb(C(20)H(23)N)Cl], the central anti-mony-containing part of the complex exhibits a pseudo-trigonal-bipyramidal geometry, where two C atoms and a lone electron pair of the Sb atom exist at the equatorial positions, while the N and Cl atoms are located at the apical positions, and a transannular inter-action exists between the Sb and N atoms on 1,5-aza-stibocine. Inter-molecular C-H?Cl hydrogen bonds are also observed.

SUBMITTER: Yi W

PROVIDER: S-EPMC3151782 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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12-Chloro-6-cyclo-hexyl-5,6,7,12-tetra-hydro-dibenzo[c,f][1,5]aza-stibocine.

Yi Weiguo W Tan Nianyuan N

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the title organometallic complex, [Sb(C(20)H(23)N)Cl], the central anti-mony-containing part of the complex exhibits a pseudo-trigonal-bipyramidal geometry, where two C atoms and a lone electron pair of the Sb atom exist at the equatorial positions, while the N and Cl atoms are located at the apical positions, and a transannular inter-action exists between the Sb and N atoms on 1,5-aza-stibocine. Inter-molecular C-H⋯Cl hydrogen bonds are also observed. ...[more]

PMID: 21836902

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