Dimethyl 8-acetyl-2-methyl-1,2-dihydro-quinoline-2,4-dicarboxyl-ate.

ABSTRACT: In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34?(2)?Å from the plane (r.m.s. deviation = 0.051?Å) defined by the N and four aromatic C atoms. Intra-molecular N-H?O hydrogen bonding generates an S(6) ring motif and the dihedral angle between the mean plane though the S(6) ring and that through the five-atom half-boat plane is 3.39?(2)°. In the crystal, weak inter-molecular C-H?O hydrogen bonds link mol-ecules into zigzag chains along [001] due to c-glide symmetry, and C-H?? inter-actions extend along [010].

SUBMITTER: Kelesoglu Z 

PROVIDER: S-EPMC3052105 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature