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(E)-N'-[(2-Hy-droxy-naphthalen-1-yl)methyl-idene]-4-methyl-benzene-sulfono-hydrazide.


ABSTRACT: In the title compound, C(18)H(16)N(2)O(3)S, the dihedral angle between the planes of the benzene ring and the naphthyl ring system is 83.37?(10)°. An intra-molecular O-H?N hydrogen bond occurs. Inter-molecular N-H?O hydrogen bonds stabilize the crystal structure. There is a ?-? inter-action between the naphthyl ring systems [centroid-centroid distance = 3.7556?(15)?Å]. In addition, naphth-yl-tolyl and naphth-yl-naphthyl C-H?? inter-actions are observed.

SUBMITTER: Shahverdizadeh GH 

PROVIDER: S-EPMC3052163 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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(E)-N'-[(2-Hy-droxy-naphthalen-1-yl)methyl-idene]-4-methyl-benzene-sulfono-hydrazide.

Shahverdizadeh Gholam Hossein GH   Bikas Rahman R   Eivazi Maryam M   Mahboubi Anarjan Parisa P   Notash Behrouz B  

Acta crystallographica. Section E, Structure reports online 20110226 Pt 3


In the title compound, C(18)H(16)N(2)O(3)S, the dihedral angle between the planes of the benzene ring and the naphthyl ring system is 83.37 (10)°. An intra-molecular O-H⋯N hydrogen bond occurs. Inter-molecular N-H⋯O hydrogen bonds stabilize the crystal structure. There is a π-π inter-action between the naphthyl ring systems [centroid-centroid distance = 3.7556 (15) Å]. In addition, naphth-yl-tolyl and naphth-yl-naphthyl C-H⋯π inter-actions are observed. ...[more]

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